Sunday
4:00 pm - 8:00 pm
Arrival and Check-in
6:00 pm - 7:00 pm
Dinner
7:30 pm - 7:40 pm
Introductory Comments by GRC Site Staff / Welcome from the GRC Chair
7:40 pm - 9:30 pm
Transition Metals in Organic Synthesis
7:40 pm - 7:45 pm
Opening Remarks
7:45 pm - 8:15 pm
"Catalysis with Metal Carbonyl Complexes"
8:15 pm - 8:30 pm
Discussion
8:30 pm - 9:00 pm
"Is Concerted-Metalation Deprotonation (CMD) a Singular C-H Activation Mechanism? Evidence for a Catalyst-Controlled Continuum"
9:00 pm - 9:15 pm
Discussion
9:15 pm - 9:30 pm
General Discussion
Monday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Group Photo
9:00 am - 12:30 pm
Catalysis with Inexpensive Metals
9:00 am - 9:30 am
"One or Two Electron Redox? Oxidation-Induced C-H Functionalization and Oxidative Cross-Coupling"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"A Metallopeptide Nitrite Reductase"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Catalysis at Metal-Metal Bonds"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Mechanistic Studies of Ti-Catalyzed Nitrene Transfer Reactions as a Platform for Reaction Discovery"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
3:00 pm - 4:00 pm
The GRC Power Hourâ„¢
The GRC Power Hourâ„¢ is designed to address challenges women face in science and issues of diversity and inclusion. The program supports the professional growth of all members of our communities by providing an open forum for discussion and mentoring.
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Electrocatalysis for Energy and Synthesis
7:30 pm - 8:00 pm
"Electrocatalytic Ammonia Splitting: Enabling the Renewable Fuel of the Future"
8:00 pm - 8:15 pm
Discussion
8:15 pm - 8:45 pm
"Molecular Catalysis of Electrochemical Reactions: Tools for Mechanism Analysis, Catalyst Optimization and Selectivity Control"
8:45 pm - 9:00 pm
Discussion
9:00 pm - 9:10 pm
"Hydrogen Evolution by the Co-Mabiq Complex: The Relevance of Ligand Non-Innocence to Reactivity"
9:10 pm - 9:15 pm
Discussion
9:15 pm - 9:25 pm
"Mimicking the Mittasch Catalyst with Macrocycle-Supported Cluster Complexes"
9:25 pm - 9:30 pm
Discussion
Tuesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Mechanisms on, in and for Materials
9:00 am - 9:30 am
"C-H Activation and Hydrogen/Deuterium (H/D) Exchange: Mechanistic Insight on Heterogeneous Catalysts"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Taking the Molecular to the Macromolecular: Inorganic Electron Transfer Catalysis in Metal Organic Frameworks"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Solid-State Molecular Organometallic Chemistry: The Importance of the Anion Microenvironment in Synthesis and Catalysis"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Mechanistic Insights into Redox-Switchable Polymerization Catalysis"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Transformations in the f-Block
7:30 pm - 8:00 pm
"Many-Electron Reductive Activation and Functionalization of Small Molecules with Dinuclear 5f-Organometallics"
8:00 pm - 8:15 pm
Discussion
8:15 pm - 8:45 pm
"Follow the Thread: Unraveling the Mechanism of Substrate Reduction by Samarium(II)-Proton Donor Complexes"
8:45 pm - 9:00 pm
Discussion
9:00 pm - 9:10 pm
"Molecular Electrocatalysts for Reductive CO2 and O2 Activation"
9:10 pm - 9:15 pm
Discussion
9:15 pm - 9:25 pm
"Oxidative Reactivity of Nitrite at Dicopper Center"
9:25 pm - 9:30 pm
Discussion
Wednesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Computational and Spectroscopic Techniques to Probe Mechanism
9:00 am - 9:30 am
"The Water Oxidation Reaction in Natural Photosynthesis"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Electronic Structures of Late Metal Complexes in Unusual Formal Oxidation States"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Fundamental Properties of C-H Bonds: Relevance to Catalytic Hydrocarbon Functionalization"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"In Dialogue with Nature: Molecules, Quantum Mechanics, Spectroscopy and Reaction Mechanisms"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:00 pm - 7:30 pm
Business Meeting
Nominations for the Next Vice Chair; Fill in Conference Evaluation Forms; Discuss Future Site and Scheduling Preferences; Election of the Next Vice Chair
7:30 pm - 9:30 pm
Mechanisms in the Second Sphere
7:30 pm - 8:00 pm
"Roles of Pyridinol-Type Ligands for CO2 Reduction and Hydrogenation"
8:00 pm - 8:15 pm
Discussion
8:15 pm - 8:45 pm
"Transition Metal Catalysts for N2 Reduction and NH3 Oxidation: Strategies for Making and Breaking N=N and N-H Bonds"
8:45 pm - 9:00 pm
Discussion
9:00 pm - 9:10 pm
"Understanding the Selectivity of Oxygen Activation by Iron-Porphyrin Catalysts"
9:10 pm - 9:15 pm
Discussion
9:15 pm - 9:25 pm
"Stabilization and Reactivity of Low-Valent Copper on Titania Aerogels"
9:25 pm - 9:30 pm
Discussion
Thursday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Uncovering Bioinorganic Reaction Mechanisms
9:00 am - 9:30 am
"Bioorganometallic Chemistry Within a Model Nickel Enzyme"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Insights into the Oxidative Mechanism of a New Class of Copper Enzymes: Lytic Polysaccharide Monooxygenases"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Defining a Substrate-Binding Site in Nitrogenases: Implications for the Mechanism of Dinitrogen Reduction"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Synthetic Fe Nitrogenases and How They Work"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Keynote Session: Enabling Mechanisms for Grand Chemical Challenges
7:30 pm - 7:40 pm
"Isolation, Characterization and Basicity Driven C-H Activation Reactivity of a Terminal Co(III)-Oxo Complex"
7:40 pm - 7:45 pm
Discussion
7:45 pm - 7:55 pm
"Understanding Catalyst Structural Effects on the Ring-Opening Transesterification Polymerization of Cyclic Esters"
7:55 pm - 8:00 pm
Discussion
8:00 pm - 8:10 pm
"Synthesis and Reactivity of M-Alkyl, M-Hydroxo and M-Amido Complexes Supported by a Dianionic Pentadentate Ligand"
8:10 pm - 8:15 pm
Discussion
8:15 pm - 9:00 pm
"Olefin Metathesis: The Gift that Keeps on Giving"
9:00 pm - 9:15 pm
Discussion
9:15 pm - 9:30 pm
Closing Remarks
Friday
7:30 am - 8:30 am
Breakfast
9:00 am
Departure