Sunday
2:00 pm - 9:00 pm
Arrival and Check-in
6:00 pm - 7:00 pm
Dinner
7:30 pm - 7:40 pm
Introductory Comments by GRC Staff / Welcome and Introduction from the Chairs
7:40 pm - 9:30 pm
Mechanisms Inspired by Biological Systems
7:40 pm - 8:10 pm
"Siderophores in Stereo: Chirality in Microbial Iron Acquisition"
8:10 pm - 8:20 pm
Discussion
8:20 pm - 8:45 pm
"Carbon Dioxide Reduction by Trinuclear Metal Complexes"
8:45 pm - 8:55 pm
Discussion
8:55 pm - 9:20 pm
"Bioinorganic and Bioorganic Chemistry of Non-Heme Iron Enzymes Catalyzed C-X Bond Forming Reactions in Natural Products"
9:20 pm - 9:30 pm
Discussion
Monday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Mechanisms in Organometallic Chemistry and Catalysis
9:00 am - 9:30 am
"Reduction of N2 to Ammonia by Pincer-Mo Complexes: A New Perspective"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Metallacyclobuta-(2,3)-Diene: A Versatile Ligand for Stream-line Synthesis of First Row Transition Metal Catalysts in Cyclic Polymerization of Phenylacetylene"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Shining Light on Stoichiometric and Catalytic Early Transition Metal Redox Chemistry"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Mechanisms Involving Metal Bound Arynes"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
3:00 pm - 4:00 pm
The GRC Power Hour™
The GRC Power Hour™ is designed to address the interests and needs of all scientists and the challenges they face in their careers. Specifically, the program promotes meaningful conversations amongst colleagues of all career stages about barriers to career advancement and strategies to support the professional growth of all members of the community. The GRC Power Hour™ is open to all conference participants.
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Mechanisms in Organic Chemistry
7:30 pm - 8:00 pm
"Alkene Hydrofunctionalization Catalyzed by Metal-Hydrides"
8:00 pm - 8:15 pm
Discussion
8:15 pm - 8:45 pm
"Mapping Catalytic Oxidative Decarboxylative Coupling Reactions"
8:45 pm - 9:00 pm
Discussion
9:00 pm - 9:10 pm
"Selective Stepwise Reduction of Nitrate and Nitrite Dinitrogen or Ammonia"
9:10 pm - 9:15 pm
Discussion
9:15 pm - 9:25 pm
"An Electrochemical Approach for Designing Thermochemical Bimetallic Nitrate Hydrogenation Catalysts"
9:25 pm - 9:30 pm
Discussion
Tuesday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Group Photo
9:00 am - 12:30 pm
Mechanisms in Computational Chemistry
9:00 am - 9:30 am
"Electrocatalytic Reduction of Carbon Dioxide by a Co(II) Phthalocyanine Catalyst on Graphitic Support"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Combined Computational and Experimental Investigation of Molecular Complexes for Ammonia Oxidation"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Modeling Catalytic Reactions in Reticular Frameworks"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"NMR Chemical Shifts beyond Numbers: A Reactivity Descriptor"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Mechanisms in Materials Chemistry
7:30 pm - 8:00 pm
"Mechanisms of Proton-coupled Electron Transfer at the Surface of Metal Oxide Clusters"
8:00 pm - 8:15 pm
Discussion
8:15 pm - 8:45 pm
"Pseudo-Elementary Steps: A Key Concept in Elucidating the Kinetics and Mechanisms of Complex Chemical Systems"
8:45 pm - 9:00 pm
Discussion
9:00 pm - 9:10 pm
"Surface-like NOx Reduction at an Atomically Precise Tricopper Cluster"
9:10 pm - 9:15 pm
Discussion
9:15 pm - 9:25 pm
"Electrocatalytic Synthesis with Interfacial Control"
9:25 pm - 9:30 pm
Discussion
Wednesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Mechanisms and Methods in Green Chemistry, Alternative Energy and Biomass Conversion
9:00 am - 9:30 am
"Quantifying Productive and Degenerate Reactions in Olefin Metathesis by Multivariable Global Kinetic Modeling"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Rationalizing the Interactions of Pnicotgen Oxides with Trivalent Lanthanides and Actinides"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Advancing Closed-Loop Chemical Recycling of Polyurethane Foams: Insights from Kinetic Studies"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Redox Switchable Catalysis"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Isotope Effects and Electrochemistry: Mechanisms and Methods
7:30 pm - 8:00 pm
"Organometallic Protonolysis and the Meaning of Large Observed Kinetic Isotope Effects"
8:00 pm - 8:15 pm
Discussion
8:15 pm - 8:45 pm
"Integrated CO2 Capture and Electrocatalytic Conversion"
8:45 pm - 9:00 pm
Discussion
9:00 pm - 9:10 pm
"Ni Imido Complexes in Non-traditional Oxidation States"
9:10 pm - 9:15 pm
Discussion
9:15 pm - 9:25 pm
"Host-Guest-Type Ligand/Metallate Complexes"
9:25 pm - 9:30 pm
Discussion
Thursday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Business Meeting
Nominations for the Next Vice Chair(s); Complete the GRC Evaluation Forms; Election of the Next Vice Chair(s)
9:00 am - 12:30 pm
Mechanisms in Polymerization Chemistry
9:00 am - 9:30 am
"Multiscale Mechanisms for Selective Deconstruction of Polyolefins"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Crystal Structure of Active Methylaluminoxane (MAO): Extractable [Al(CH3 )2 ]+ for Pre-Catalyst Activation"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"CO2 and Epoxide Copolymerization Catalyzed by Main Group Compounds"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Leveraging Organometallic Mechanisms to Design Degradable Polymers from C1 Sources"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Keynote Session: 25 Years of Mechanisms on X-H Bond Activation, and Catalytic Dehydration
7:30 pm - 8:15 pm
"Catalysis with First-Row Transition Metal Complexes"
8:15 pm - 8:30 pm
Discussion
8:30 pm - 8:40 pm
"Elucidating the Active Site in Heterogenous OH-Directed Hydrogenation using Pt-Cu Bimetallic Catalysts"
8:40 pm - 8:45 pm
Discussion
8:45 pm - 8:55 pm
"Mechanistic and Kinetic Investigation into the Hydroboration Chemistry of PPCF3PCoI2"
8:55 pm - 9:00 pm
Discussion
9:00 pm - 9:20 pm
Late-Breaking Topic
9:20 pm - 9:30 pm
Discussion
Friday
7:30 am - 8:30 am
Breakfast
9:00 am
Departure